Peculiar Petunia
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I found this when searching for how to make chloroform:
CHLOROFORM IS A LIQUID ONCE USED AS AN ANESTHETIC, AND A SOLVENT FOR SPECIMEN PRESERVATION. IT FINDS USES TODAY IN ORGANIC CHEMISTRY AS A SOLVENT BUT LITTLE ELSE DUE TO THE EMERGENCE OF LESS DANGEROUS ALTERNATIVES. CHLOROFORM'S CHEMICAL FORMULA IS CHCl3 AND IT BOILS WITH SLIGHT WARMING TO 61 CELSIUS.
CHLOROFORM CAN BE PRODUCED WITH A SIMPLE REACTION BETWEEN HYPOCHLORITE AND ACETONE. HYPOCHLORITE CAN BE FOUND IN POOL SHOCK AND BLEACH AS SODIUM OR CALCIUM SALTS. THE REACTION IS HIGHLY EXOTHERMIC, SO THE REACTION MUST BE KEPT COOL TO PREVENT VAPORIZATION OF THE FORMED CHLOROFORM, OR WORSE, BOILING OF THE SOLUTION. THE FORMED CHLOROFORM IS CONTAMINATED WITH WATER AND SOME SALTS, WHICH CAN BE REMOVED BY VACUUM FILTERING AND DRYING WITH MAGNESIUM SULFATE.
CHLOROFORM PRODUCED IN THIS MANNER CAN BE USED TO SOLVENT WELD PLASTICS LIKE ACRYLIC (ANY APPLICATION WHERE DCM, DICHLOROMETHANE IS NORMALLY USED) OR TO PRESERVE SPECIMENS LIKE INSECTS.
NOTE: AS DESCRIBED THE REACTION DOES NOT PRODUCE ENOUGH CHLOROFORM FOR EXTRACTION. YOU'LL NEED TO USE AT LEAST A GALLON OF BLEACH AT A TIME (AND SUITABLE AMOUNT OF ACETONE) IN ORDER TO RECOVER ANY USEABLE QUANTITY OF CHLOROFORM.[/B]
MATERIALS
-BLEACH OR POOL SHOCK (LIQUID)
-ACETONE (NOT NAIL POLISH REMOVER)
-ICE!! LOTS AND LOTS OF ICE.
EQUIPMENT
-MISC. GLASSWARE
The 2 areas that I bolded (well I thought that I bolded, oh well to lazy to fix it) are interesting. You would have to mix a gallon of bleach at a time to get enough chloroform. And it is volatile and would need to be kept very cool, then the ice.
Not sure that you would clean up anything with that much materials. A gallon or more of bleach and acetone? That is a lot of cleaning materials!
Thanks for finding the quote about the acetone. No nail polish remover handy here, but I thought the chemical composition was changed in the '80s or '90s away from acetone. It's easy enough to find in a paint store, though.