A quick search says that snapchat cannot be accessed from 2 phones simultaneously. Given that most people using snapchat keep the app open and running even when not actively sending snaps this seems unlikely. MOO.
but if our POI is the one who sent the snap, all he'd have to do is log mollie's phone out of the app and into his or her own phone.
like any app, even though linked to your phone and likely your computer, you have a login that is either your apple ID, facebook account or its own separate login for the app. there may be some hiccups with this (such as what you mention above) but it seems like an amateur hurdle (aka your average millenial could figure out). i have definitely logged into friends apps on my phone and vice versa for random reasons. not saying this happened or is likely, but possible.
one thing that intrigues me about this case is that not only did she vanish without a trace, it leaves us relying on technology so heavily. and imo, its a blessing and a curse. technology can tell us so much but at the same time there are so many hacking options and loopholes, i dont find its answers definitive enough to give me comfort unless they come directly from snapchat/app company and/or LE.