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Why would darts expire? The controlled RX used in them would have an expiration date. I think BM kept the darts at PP. I think he used them on his deer farm and was familiar with their use. Where and when he obtained a drug to use in them is still unknown. But he could have had legal access to an RX in Indiana that he brought to PP. His weapon of choice was probably based on knowledge, access and convenience. I'll be surprised if he had to pilfer either. I'll also be surprised if the defense can place any of it in someone else's hands.
JMO
I don't think anyone means the phrase "darts expire" to mean that the actual plastic and needle expires. I think if the phrase is used, it's generally understood to mean the contents of the dart expire.
You're right that he could have had an Rx in Indiana. Or he could have bought it online where an online vet approves use.
Or he could have just gotten it in Mexico. Or on the street. I doubt LE knows exactly what he used.
My question is whether shooting a plastic dart through a .22 rifle would leave discernible plastic in the rifle. My bet is that it would.