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Parents, particularly with younger children, sometimes subdue the kids with drugs or suffocation, and then finish the deed by drowning them.
http://m.ajc.com/news/news/testimony-former-cobb-mom-planned-childrens-murder/nhpnT/
http://bnonews.com/urgent/6202/moth...ating-them-before-placing-car-into-the-river/
How about suffocation by drugs? A drug like succinylcholine could lead to asphyxiation and would be difficult to detect.
https://writersforensicsblog.wordpr...cinylcholine-is-it-the-perfect-murder-weapon/